(i) (ii) Excess Zinc carbonateis used to make sure that all the hydrochloric acid arecompletelyneutralised.
(iii)Firstly, fliter out the excess zinc carbonatefrom the solution and the zinc chloridesolution will be left.Zince chloride crystals can be obtained byevaporatingthe Zincchloride salutionto saturatedand allow the sartuated zinc chloride solution tocool down.Crystals of zinc chloridewill be formed.
(i) Potassium sulfate is aGroup(I)soluble salt. Titrationis recommended for preparation ofallGroup (I) saltsas they aresoluble. As thesolutions usedare colourless, indicatioris alsoused toidentify the end point of neutralizationbetween sulfuric acid (colourless) andpotassium hydroxide (colourless)where the solutionwith indicator turnscolourless.